STADIE RESEARCH GROUP
Our research spans the fields of solid-state, physical, and materials chemistry. We explore new synthesis routes toward structurally and chemically tunable carbon-based materials with a chief interest in their application for energy storage. Contributing fundamental insights into gas physisorption phenomena at the solid interface is also a goal of our work, using classical equilibrium thermodynamics and statistical mechanics.
We are now a "one year old" research group, having kicked off in January 2017. Lab rotations in our group are underway and we are looking for team members with enthusiasm for hands-on projects ranging from gas manifold apparatus design/construction (some have jokingly called this "space plumbing") to classic solid-state chemistry (quartz-blowing and high-temperature synthesis). Gas adsorption measurements are a "bread and butter" activity in this group spanning almost all projects. Our theoretical department is also seeking keen minds with an interest in thermodynamics and statistical mechanics to answer frontier questions in adsorptive energy storage at high pressures. Our work covers a lot of different bases - rotate in and take a look!
Work With Us!
Our group is seeking PhD students; if your interests are well-aligned with our activites, please contact Nick directly. For more information on pursuing a PhD in our department, check out the [Chemistry Admissions] page. Those interested in an interdisciplinary, materials-focused curriculum should check out the newly developed [Materials Science] program. Both programs are relevant to our group.
We are very excited to host undergraduate projects that fall within the general outline of our work. This includes students from abroad seeking international laboratory experience in the western US (e.g., Master's thesis projects). Please contact Nick directly or stop by the lab.
We do not currently have an open postdoctoral position, but applications for funding would be enthusiastically supported in relevant cases.
- Jun 22nd 2018 Phosphorus-Doped Graphitic Carbon
Manuscript accepted: we report a fast, cheap, and simple new synthesis route to high phosphorus-content graphitic carbon, PCx, directly from two liquid precursors (benzene and phosphorus trichloride). This material is produced in bulk form (as opposed to as a thin-film) permitting its use in batteries or as an electrocatalyst. Interestingly, stabilized white phosphorus (P4) also exists in some form in all of the materials we make by this route, which opens up all sorts of interesting paths forward! Details to follow shortly.
- Jun 11th 2018 First Grant Received
We are grateful to receive our first seed of support in the form of a [Petroleum Research Fund (PRF)] grant from the American Chemical Society. This work seeks to investigate the role of heteroatom dopants in advanced porous carbon adsorbents designed for high-pressure methane storage near ambient temperature. The fire has been stoked!
- May 25th 2018 Kaitlin Nails It
Congrats to Erin and Kaitlin G. who are officially producing pristine FAU-type zeolite-templated carbon (ZTC) on our custom low-pressure CVD apparatus. And, for Kaitlin, on the first try (with a little help from Erin...) no less. We're cookin' with gas, literally! Stay tuned for all sorts of new applications for these ultraporous carbon framework materials...
- Apr 26th 2018 Undergraduate Awards
Hearty congratulations to our well-decorated team of undergrads (Kaitlin B., Kaitlin G., Seth, Hans, and Rylan) who cleaned up at the Awards Ceremony this warm Thursday evening, and especially to Kaitlin B. who will be graduating next weekend. We wish you all the best. It's now so close to the best time of the year, and we anticipate an action packed summer of research and adventures in the local playground that is southwestern Montana.
- [News Archive]
- NOVEL GRAPHITE-LIKE MATERIALS In 2016, three researchers at ETH Zürich discovered a new direct synthesis route to bulk, high boron-content graphitic carbon... [continued here]
- HIGH-PRESSURE HYDROGEN STORAGE At pressures above 10 MPa (~100 atm) at room temperature, hydrogen becomes significantly non-ideal... [continued here]
- ZEOLITE-TEMPLATED CARBON Synthesized by chemical vapor deposition (CVD) within the pores of a zeolite template (a crystalline, microporous tectoaluminosilicate material), ZTCs are... [continued here]
- NOVEL SUPERCRITICAL SOLVENTS In 2014, we discovered nitrogen to be an effective solvent for the purification of porous, reactive gamma-phase magnesium borohydride... [continued here]
- N. P. Stadie, E. Billeter, L. Piveteau, K. Kravchyk, M. Döbeli, M. V. Kovalenko, “Direct Synthesis of Bulk Boron-Doped Graphitic Carbon” Chem. Mater., 29 (7), 3211-3218 (2017) [link]
- N. P. Stadie, S. Wang, K. V. Kravchyk, M. V. Kovalenko, “Zeolite-Templated Carbon as an Ordered Microporous Electrode for Aluminum Batteries” ACS Nano, 11 (2), 1911-1919 (2017) [link]
- N. P. Stadie, M. Murialdo, C. C. Ahn, B. Fultz, “Unusual Entropy of Adsorbed Methane on Zeolite-Templated Carbon” J. Phys. Chem. C, 119 (47), 26409-26421 (2015) [link]
- N. P. Stadie, E. Callini, B. Richter, T. R. Jensen, A. Borgschulte, A. Züttel, “Supercritical N2 Processing as a Route to the Clean Dehydrogenation of Porous Mg(BH4)2” J. Am. Chem. Soc., 136 (23), 8181-8184 (2014) [link]
- N. P. Stadie, M. Murialdo, C. C. Ahn, B. Fultz, “Anomalous Isosteric Enthalpy of Adsorption of Methane on Zeolite-Templated Carbon” J. Am. Chem. Soc., 135 (3), 990-993 (2013) [link]